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Synthesis, characterization, and heterogeneous catalysis of polymer‐supported poly(propyleneimine) dendrimer stabilized gold nanoparticle catalyst

Identifieur interne : 000072 ( Main/Exploration ); précédent : 000071; suivant : 000073

Synthesis, characterization, and heterogeneous catalysis of polymer‐supported poly(propyleneimine) dendrimer stabilized gold nanoparticle catalyst

Auteurs : Eagambaram Murugan [Inde] ; Rajmohan Rangasamy [Inde]

Source :

RBID : ISTEX:482804DDFF88E13BF02DED77C3D7F69364877D54

English descriptors

Abstract

We report here, the synthesis of two types of heterogeneous nanoparticle catalysts viz., polymer‐supported poly(propyleneimine)‐G2 dendrimer stabilized gold nanoparticle catalysts using crosslinked poly(4‐vinylpyridine) matrix (PSP4VP) as support material. The grafting of dendrimer on the surface of P4VP beads was characterized by FTIR spectrophotometer and CHN analyses. The immobilization of AuNPs was characterized by UV‐Vis spectrum, SEM, and HRTEM studies. The resultant polymer‐supported dendrimer stabilized AuNPs were used as a heterogeneous catalyst for the reduction of 4‐nitrophenol. The catalytic activity is found to be excellent and it can also be reused many times by simple filtration and activity remains maintained. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 2525–2532, 2010

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DOI: 10.1002/pola.24028


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<div type="abstract" xml:lang="en">We report here, the synthesis of two types of heterogeneous nanoparticle catalysts viz., polymer‐supported poly(propyleneimine)‐G2 dendrimer stabilized gold nanoparticle catalysts using crosslinked poly(4‐vinylpyridine) matrix (PSP4VP) as support material. The grafting of dendrimer on the surface of P4VP beads was characterized by FTIR spectrophotometer and CHN analyses. The immobilization of AuNPs was characterized by UV‐Vis spectrum, SEM, and HRTEM studies. The resultant polymer‐supported dendrimer stabilized AuNPs were used as a heterogeneous catalyst for the reduction of 4‐nitrophenol. The catalytic activity is found to be excellent and it can also be reused many times by simple filtration and activity remains maintained. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 2525–2532, 2010</div>
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